A Method of determining "a" of van der Waals' equation
نویسندگان
چکیده
منابع مشابه
Generalized van der Waals equation of state*
The quantitative thermodynamic effect of adding a weak, long-range attraction to inverse-power repUlsive potentials is studied. The resulting phase diagrams exhibit two fluid phases and a solid phase. a critical point, a triple point, and, for sufficiently soft repulsions, an additional solid phase with an additional triple point. The effects of attractions other than van der Waals' are studied...
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In the present work, a modified equation of state has been presented for the calculation of volumetric properties of supercritical fluids. The equation of state is van der Waals basis with temperature and density-dependent parameters. This equation of state has been applied for predicting the volumetric properties of fluids. The densities of fluids were calculated from the new equation of state...
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In this study a simple and general chemical association theory is introduced. The concept of infinite equilibrium model is re-examined and true mole fractions of associated species are calculated. The theory is applied to derive the distribution function of associated species. As a severe test the application of presented theory to the van der Waals mixture model is introduced in order to p...
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The thermodynamic properties, enthalpy of vaporization, entropy, Helmholtz function, Gibbs function, but especially the heat capacity at constant volume of a van der Waals gas (and liquid) at the phase transition are examined in two different limit approximations. The first limit approximation is at the near-critical temperatures, i.e., for T/Tc → 1, where Tc is the critical temperature, the ot...
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ژورنال
عنوان ژورنال: The Journal of Physical Chemistry
سال: 1913
ISSN: 0092-7325,1541-5740
DOI: 10.1021/j150137a002